2-Ethoxy-6-({2-[(3-ethoxy-2-hydroxybenzylidene)amino]benzyl}iminomethyl)phenol
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چکیده
منابع مشابه
N′-(3-Ethoxy-2-hydroxybenzylidene)benzenesulfonohydrazide
There are two mol-ecules in the asymmetric unit of the title compound, C(15)H(16)N(2)O(4)S, both of which are stabilized by an intra-molecular O-H⋯N hydrogen bond. Inter-molecular N-H⋯O hydrogen bonds lead to [101] chains of mol-ecules in the crystal structure.
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4,6-Dichloro-2-(methylthio)pyrimidine (3) reacts with EtONa in EtOH, at ca. 20 ◦C, for 2 h, to give exclusively 4-chloro-6-ethoxy-2-(methylthio)pyrimidine (5) in 89% yield. The latter is presented as a useful multifunctionalised pyrimidine scaffold.
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Isolated guanidinium ions and tetra-phenyl-borate ions are present in the crystal structure of the title compound, C(11)H(22)N(3)O(2) (+)·C(24)H(20)B(-). In the guanidinium ion, the dihedral angle between the N/C/N and C/C/C planes being 49.9 (1)°. The six-membered ring exhibits a half-chair conformation. The C-N bond lengths in the cation range between 1.3335 (16) and 1.3552 (16) Å, indicating...
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The syntheses of the title compounds are described. 1- [[2- Amino -1 - (hydroxymethyl) ethoxy] methyl] uracil exhibitslittleactivity against herpesviruses (HSV) in vivo
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In the mol-ecule of the title compound, C(16)H(19)N(3)O(6), the imidazole ring is essentially planar [maximum deviation = 0.002 (2) Å] and forms a dihedral angle of 5.08 (14)° with the nitro group. In the crystal structure, adjacent mol-ecules are connected via inter-molecular C-H⋯O hydrogen bonds into columns parallel to the a axis.
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2012
ISSN: 1600-5368
DOI: 10.1107/s1600536812031479